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Acetal homopolymer vs. copolymer

POM-H vs. POM-C: strength, stability and which suits your part.

The short answer

Acetal homopolymer is a little stiffer, stronger and harder, and is often chosen for gears and highly loaded parts. Acetal copolymer is more stable in hot water, chemicals and the molding barrel, and easier to process. For most general parts either works.

Acetal (POM) is the go-to resin for precision mechanical parts: low friction, stable dimensions and good wear. It comes in two families, and the choice affects strength, chemical resistance and how forgiving the material is in the press.

Side by side

PropertyHomopolymerCopolymer
StructureSingle repeating unitSmall share of a second unit for stability
Stiffness and strengthHigherSlightly lower
Hardness and creep resistanceHigherSlightly lower
Fatigue resistanceHigherGood
Hot water and alkalisFairBetter
Thermal stability in the barrelNarrower windowMore forgiving
Melting point~175°C~165°C
Mold shrinkage~1.9–2.3%~1.8–2.2%
Typical usesGears, high-load snap fits, fastenersPlumbing, food equipment, pump parts, clips

Typical values for general-purpose, unfilled grades. Individual grades vary; check the data sheet.

Choose homopolymer when

  • Gears and parts under steady load
  • Snap fits and springs that need high stiffness and fatigue life
  • Maximum hardness and creep resistance matter

Choose copolymer when

  • Hot water, steam or cleaning chemicals are involved
  • Long barrel residence or thick parts make processing tricky
  • Plumbing, food equipment and pump parts

Processing notes

  • Keep melt temperature and residence time within the data sheet; overheated acetal releases formaldehyde.
  • Homopolymer is less tolerant of long residence times than copolymer.
  • Never run acetal and PVC through the same barrel without a full purge; the combination can release corrosive gas.
  • Most standard grades need little or no drying; toughened grades usually do. See the drying chart.

Grades we source

We source acetal homopolymer and copolymer, including lubricated, toughened and glass-filled grades, from one gaylord up, with a COA on every lot, tested to ASTM or ISO methods. See acetal (POM) and acetal vs. nylon.

Common questions

What is the difference between acetal homopolymer and copolymer?

Homopolymer is made of one repeating unit and is slightly stiffer, stronger and harder. Copolymer includes a small share of a second unit that makes it more stable in hot water, chemicals and long melt residence.

Which acetal is stronger?

Homopolymer, by a modest margin in stiffness, tensile strength and fatigue. It is often chosen for gears and highly loaded snap fits.

Is copolymer acetal better for hot water and chemicals?

Yes. Copolymer resists hot water, steam and strong alkalis better and is less prone to degrading when it sits in the barrel. It is often chosen for plumbing, food equipment and parts that see cleaning chemicals.

Do the two process differently?

Homopolymer has a narrower processing window and degrades faster if it overheats or sits in the barrel too long. Copolymer is more forgiving. Never mix acetal with PVC in the same barrel; the combination can release corrosive gas.

Can I swap homopolymer for copolymer?

Often, with checks. Expect slightly lower stiffness and a small shrinkage difference going to copolymer. Measure first parts and requalify where approvals are tied to the grade.

Quote request · Acetal (POM)

Tell us the acetal grade you run now

A polymer chemist reviews every request, then matches your grade or finds a qualified equivalent and prices it.

No account needed · No obligation · U.S. & Canada only · Orders from one gaylord

What to send for an accurate quote
  • The grade name, from any supplier, or a data sheet
  • Color (natural, black or a custom match)
  • Fill type and percentage, if any
  • Melt flow, if you know it
  • Quantity for this order and what you use in a year
  • Ship-to city and state or province

Acetal homopolymer and copolymer, quoted

Send the acetal grade you run, and a polymer chemist will match it or suggest the other family if it fits better.

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